Search results for "charge distribution"

showing 9 items of 9 documents

Valence Topological Charge-Transfer Indices for Dipole Moments

2003

Valence topological charge-transfer (CT) indices are applied to the calculation of dipole moments. The dipole moments calculated by algebraic and vector semisums of the CT indices are defined. The combination of the CT indices allows the estimation of the dipole moments. The model is generalized for molecules with heteroatoms. The ability of the indices for the description of the molecular charge distribution is established by comparing them with the dipole moment of the valence-isoelectronic series of benzene and styrene. Two CT indices, μ v e c (vector semisum of vertex-pair dipole moments) and μ V v e c (valence μ v e c ) are proposed. μ v e c and μ V v e c are important for the predicti…

Protein ConformationHeteroatomPharmaceutical ScienceBiochemistryAnalytical ChemistryElectricityComputational chemistryDrug DiscoveryPhysicsvalence topological charge-transfer indexChemistryCharge densityGeneral Medicinemolecular charge distributionCondensed Matter Physicstransdermal drug deliveryChemistry (miscellaneous)Molecular MedicineAtomic physicsInformation SystemsSteric effectsBond dipole momentStatic ElectricityTransition dipole momentBiophysicsElectronsFractal dimensionMolecular physicsBiophysical PhenomenaArticleCatalysislcsh:QD241-441Inorganic Chemistrylcsh:Organic chemistryAtomic orbitalMoleculePhysical and Theoretical ChemistryMolecular BiologyStyreneTopological quantum numberDipole momentModels StatisticalValence (chemistry)Chemical polarityOrganic ChemistryBenzeneModels Theoreticalvalence topological chargetransfer indexElectric dipole momentDipolephenyl alcoholModels ChemicalMoment (physics)Electric dipole transitionMolecules
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Precision measurements of the charge radii of potassium isotopes

2019

International audience; Precision nuclear charge radii measurements in the light-mass region are essential for understanding the evolution of nuclear structure, but their measurement represents a great challenge for experimental techniques. At the Collinear Resonance Ionization Spectroscopy (CRIS) setup at ISOLDE-CERN, a laser frequency calibration and monitoring system was installed and commissioned through the hyperfine spectra measurement of $^{38–47}$K. It allowed for the extraction of the hyperfine parameters and isotope shifts with better than 1 MHz precision. These results are in excellent agreement with available literature values and they demonstrate the suitability of the CRIS tec…

PhysicsIsotope010308 nuclear & particles physicsNuclear structure[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]Nuclear Structure01 natural sciences7. Clean energyEffective nuclear chargeSpectral linenuclear charge distributionIsotopes of potassium0103 physical sciencesCalibrationlaser spectroscopyNuclear Physics - Experimentfine and hyperfine structurePhysics::Atomic Physicsatomic spectraAtomic physics010306 general physicsSpectroscopyydinfysiikkaHyperfine structurePhysical Review C
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Measurement of higher cumulants of net-charge multiplicity distributions in Au+Au collisions at √sNN = 7.7-200 GeV

2016

We report the measurement of cumulants (Cn,n = 1,...,4) of the net-charge distributions measured within pseudorapidity (|η| < 0.35) in Au + Au collisions at √sNN = 7.7–200 GeV with the PHENIX experiment at the Relativistic Heavy Ion Collider. The ratios of cumulants (e.g., C1/C2, C3/C1) of the net-charge distributions, which can be related to volume independent susceptibility ratios, are studied as a function of centrality and energy. These quantities are important to understand the quantum-chromodynamics phase diagram and possible existence of a critical end point. The measured values are very well described by expectation from negative binomial distributions. We do not observe any nonmono…

baryon chemical potentialsAu+Au collisionsNuclear Experimentnet-charge distributions
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Collinear Resonance Ionization Spectroscopy of Neutron-Deficient Francium Isotopes

2013

The magnetic moments and isotope shifts of the neutron-deficient francium isotopes 202-205Fr were measured at ISOLDE-CERN with use of collinear resonance ionization spectroscopy. A production-to-detection efficiency of 1% was measured for 202Fr. The background from nonresonant and collisional ionization was maintained below one ion in 105 beam particles. Through a comparison of the measured charge radii with predictions from the spherical droplet model, it is concluded that the ground-state wave function remains spherical down to 205Fr, with a departure observed in 203Fr (N = 116). ispartof: Physical Review Letters vol:111 issue:21 pages:212501-4 ispartof: location:United States status: pub…

PhysicsMagnetic moment010308 nuclear & particles physicsSpin parity and isobaric spinOther Fields of PhysicsGeneral Physics and AstronomyCharge densitychemistry.chemical_element[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]01 natural sciencesIonFranciumElectromagnetic moments190 ≤ A ≤ 219 isotpeschemistryIonization0103 physical sciencesNeutronCharge distributionPhysics::Atomic PhysicsAtomic physics010306 general physicsSpectroscopyWave functionNuclear Experiment
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Acid–Base Properties and Surface Charge Distribution of the Water-Soluble Au102(pMBA)44 Nanocluster

2016

The pKa of the p-mercaptobenzoic acid (pMBA) ligands in the Au102(pMBA)44 nanocluster was measured by using acid–base and IR titration. The observed macroscopic pKa = 6.18 ± 0.05 is significantly more basic than that of free pMBA (pKa = 4.16), and the protonation behavior is anticooperative according to the Hill coefficient n = 0.64 ± 0.04. The cluster is truly water-soluble when more than 22 and insoluble when fewer than 7 ligands are in the deprotonated state. In order to obtain more insight into the anticooperative character, the cluster was modeled at pH ∼6.2 using constant pH molecular dynamics simulations. The pKa values of the individual pMBAs are in the range of 5.18–7.58, depending…

Base (chemistry)acid–base propertiesInorganic chemistryProtonation02 engineering and technology010402 general chemistry01 natural sciencescharge distributionMolecular dynamicsDeprotonationCluster (physics)Surface chargePhysical and Theoretical Chemistryta116chemistry.chemical_classificationChemistryCharge density021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsGeneral EnergyPhysical chemistryTitration0210 nano-technologygold nanoclustersJournal of Physical Chemistry C
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Sudden change in the nuclear charge distribution of very light gold isotopes

1987

4 pages, 3 tables, 2 figures.-- PACS nrs.: 21.10.Ft, 21.10.Ky, 27.70.+q.

PhysicsGeneral Physics and AstronomyCharge densityRadiusPhotoionizationEffective nuclear chargeTime of flight[PACS] Electromagnetic momentsIonization[PACS] Charge distribution150 ≤ A ≤ 189 [[PACS] Properties of specific nuclei listed by mass ranges]Nuclear Physics - ExperimentPhysics::Atomic PhysicsIsotopes of gold[PACS] Properties of specific nuclei listed by mass ranges:150 ≤ A ≤ 189Atomic physicsHyperfine structure
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Density distributions in the $B$ meson

2016

We report on a two-flavor lattice QCD study of the axial, charge and matter distributions of the $B$ meson and its first radial excitation. As our framework is the static limit of Heavy Quark Effective Theory (HQET), taking their Fourier transform gives access to several form factors at the kinematical point $q^2=0$. Moreover they provide some useful information on the nature of an excited state, i.e. a radial excitation of a quark-antiquark bound state or a multihadron state.

Particle physicsquark antiquark: bound stateMesonHigh Energy Physics::LatticeFOS: Physical sciencescharge distribution01 natural sciencesfermion: cloverpi: couplingsymbols.namesakeHigh Energy Physics - LatticeHigh Energy Physics - Phenomenology (hep-ph)density: spatial distributionquark: flavor: 2excited state0103 physical sciencesBound stateB meson010306 general physicscharge: axialform factorPhysicsHeavy Quark Effective Theory[PHYS.HLAT]Physics [physics]/High Energy Physics - Lattice [hep-lat]finite size: effect010308 nuclear & particles physicsHigh Energy Physics::PhenomenologyHigh Energy Physics - Lattice (hep-lat)Form factor (quantum field theory)[ PHYS.HLAT ] Physics [physics]/High Energy Physics - Lattice [hep-lat]Charge (physics)Lattice QCDHigh Energy Physics - PhenomenologyFourier transformkinematicsmatter: distribution function[PHYS.HPHE]Physics [physics]/High Energy Physics - Phenomenology [hep-ph]bottom mesonExcited statesymbols[ PHYS.HPHE ] Physics [physics]/High Energy Physics - Phenomenology [hep-ph]High Energy Physics::Experimentquark: Wilsonquantum chromodynamics: lattice
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Valence Topological Charge-Transfer Indices for Reflecting Polarity: Correction for Heteromolecules

2005

Valence topological charge-transfer (CT) indices are applied to the calculation of dipole moments mu. The mu calculated by algebraic and vector semisums of the CT indices are defined. The model is generalized for molecules with heteroatoms and corrected for sp(3)-heteromolecules. The ability of the indices for the description of the molecular charge distribution is established by comparing them with mu of the valence-isoelectronic series of cyclopentadiene, benzene and styrene. Two CT indices, mu(vec) (vector semisum of vertex-pair mu) and mu(vec)V (valence mu(vec)) are proposed. The mu(vec) behaviour is intermediate between mu(vec) and mu(experiment). The correction is produced in the corr…

Steric effectsHeteroatomBiophysicsPharmaceutical ScienceElectronsFluorescence PolarizationMolecular physicsArticleBiophysical PhenomenaAnalytical ChemistryValence topological charge-transfer indexElectronegativitylcsh:QD241-441Atomic orbitallcsh:Organic chemistryHeterocyclic CompoundsReference ValuesComputational chemistryDrug DiscoveryCharge distributionPhysical and Theoretical ChemistryTopological quantum numberDipole momentValence (chemistry)ChemistryOrganic ChemistryCharge densityBenzeneModels TheoreticalDipoleChemistry (miscellaneous)HeteroatomMolecular MedicineIsolelectroic seriesMolecules
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Probing Surface Quantum Flows in Deformed Pygmy Dipole Modes

2017

In order to explore the nature of collective modes in weakly bound nuclei, we have investigated deformation effects and surface flow patterns of isovector dipole modes in a shape-coexisting nucleus $^{40}$Mg. The calculations were done in a fully self-consistent continuum finite-amplitude Quasiparticle Random Phase Approximation (QRPA) in a large deformed spatial mesh. An unexpected result of pygmy and giant dipole modes having disproportionate deformation splittings in strength functions was obtained. Furthermore, the transition current densities demonstrate that the long-sought core-halo oscillation in pygmy resonances is collective and compressional, corresponding to the lowest excitatio…

NEUTRON DRIP-LINENuclear TheoryFOS: Physical sciencesresonance reactions114 Physical sciences01 natural sciencesMolecular physicsNuclear Theory (nucl-th)nuclear charge distribution0103 physical sciencescollective levelsNuclear drip line010306 general physicsQuantumEXCITATIONSPhysicsta114nuclear density functional theoryNUCLEICondensed matter physicsIsovector010308 nuclear & particles physicsOscillationDipoleQuasiparticleRandom phase approximationExcitation
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